A revolutionary method for the recovery of metals has been developed by scientists at the National Metallurgical Laboratory (NML) in India. Using low-temperature sulfuric acid baking followed by a mild leaching process, the researchers were able to dissolve metals from pre-oxidized refinery plant spent Co-Mo/Al2O3 catalyst. The direct sulfuric acid leaching of the same sample produced poor recoveries of aluminum and molybdenum, whereas leaching after sulfuric acid baking significantly improved the recoveries of these two metals.The pre-oxidized spent catalysts used in this study were obtained from a Korean refinery plant and found to contain 40% aluminum, 9.92% molybdenum, 2.28% cobalt, 2.5% carbon, and trace amounts of other elements such as iron, nickel, sulfur, and R XRD. The host matrix was identified to be poorly crystalline gamma-Al2O3.The researchers studied the effect of various baking parameters such as catalyst-to-acid ratio, baking temperature, and baking time on the percentage dissolution of metals. They observed that the dissolution of metals increases with an increase in the baking temperature up to 300 degrees Celsius, after which it decreases with further increases in the baking temperature. Under optimum baking conditions, more than 90% of cobalt and molybdenum, and 93% of aluminum could be dissolved from the spent catalyst with the following leaching conditions: H2SO4 = 2% (v/v), temperature = 95 degrees Celsius, time = 60 minutes, and pulp density = 5%.This method has the potential to revolutionize the metal recovery industry by offering a more efficient and cost-effective process for the recovery of valuable metals from spent catalysts. This will also reduce the negative impact of spent catalysts on the environment, as they will no longer have to be disposed of in landfills.The NML is one of India's leading research institutes in the field of metallurgy, materials science, and engineering, and this discovery demonstrates its ongoing commitment to advancing the field. The institute is dedicated to research and innovation in the metallurgical industry and has a history of developing cutting-edge technologies that benefit the Indian economy.Furthermore, the NML is also involved in providing consultation services to industries and government agencies, making it a key player in shaping the Indian economy and industrial landscape. In addition to metal recovery, the institute is also engaged in research and development in areas such as corrosion science, welding technology, and non-ferrous metallurgy.The success of the method developed by the NML team demonstrates the institute's ability to leverage its expertise in the field of metallurgy to find solutions to some of the most pressing challenges facing society today. The potential of this discovery to benefit industry and the environment cannot be overstated, and it is a testament to the ongoing dedication of the NML to advancing the field of metallurgy and materials science.In conclusion, the development of a new and more efficient method for the recovery of valuable metals using low-temperature sulfuric acid baking and mild leaching represents a major breakthrough in the field of metallurgy. This discovery has the potential to revolutionize the metal recovery industry by offering a more efficient and cost-effective process for the recovery of valuable metals from spent catalysts, ultimately reducing the negative impact of spent catalysts on the environment. The NML's commitment to research and innovation continues to be a driving force in shaping the Indian economy and industrial landscape.
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